Is it possible to use the Vinmetrica SC-50 for analyzing MALIC ACID levels on grapes (pre-harvest grape sampling), besides using it later for MLF assessment?

Absolutely! You expect that malic acid levels will be around 1 to 2 g/L in most wine varietals prior to MLF,  and in extreme cases it could go above 3 g/L which might cause the response of the SC-55 unit to exceed its linear range.  In that case you should repeat the test on a diluted sample  – take 5.0 mL of the boiled, reconstituted wine/must sample and dilute it with 5.0 mL DI water.  Then take 5 mL of that dilution and add 5 mL Assay Diluent just as you would in the normal procedure.  Multiply any calculation, if you are doing quantitative mode, by an additional factor of 2.