The pH 4 reference solution (for use with the SC-200 or SC-300 unit + pH electrode) is now labeled as 4.00, the correct reference value at a temperature of 20 ℃ (68 ℉).  The chemical composition of the solution itself is unchanged from before, and its reference value is still 4.01 at 25 ℃ (77 ℉). It’s just that since most of us work on wine or other beverages that are closer to 15 to 20 ℃ (59 to 68 ℉), a value of 4.00 is slightly more accurate than 4.01. Instruments that use the old reference value 4.01 rather than the new value of 4.00 do not produce significant error: less than 0.02 pH difference in wines with pH values from 3.00 to 4.00.

As mentioned in a recent newsletter, we have a new update to the firmware for SC-200s and -300s built after 2015 (Serial numbers 2897 and above for SC-300s, 470 and above for SC-200s).  This new firmware, versions 3.2.F (or 2.2.F for an SC-200) and higher, uses the value of 4.00 instead of 4.01 for pH calibration.  All new units being shipped will now have this new firmware version installed on them. If your instrument has a lower serial number, or an earlier version of firmware, it will set the pH 4 reference to 4.01 as usual.

For those us of in the northern hemisphere it is time we start getting ready for harvest season!

WineMaker Magazine has a great Harvest Check List in their most recent edition, written by Bob Peak. It is wonderfully detailed and a must read for all our customers. It is an all encompassing check list whereas ours will just scratch the surface. Our checklist reflects only what we do here at our own winery. What you do during your own harvest is up to you.

We always use a checklist to prepare and to ensure we have everything we need for a successful harvest. Our winery, Little Oaks Winery, is a small operation with a limited about of employees and we have found that preparing for harvest is essential for producing award-winning, memorable wines. Our winery is about four to five weeks away from harvest time. It’s time to start preparing.

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Wine is an acidic substance, and there are ranges of acidity that are appropriate to each varietal.  In general a wine that is too acidic will taste sharp or sour, while one that is not acidic enough will taste flat and insipid. It’s no surprise to those of you on the quest for great achievements in winemaking that pH and acidity (TA) are important aspects that are key to know and control.  In a previous issue of The Wine Analyst’s Blog (April_pH_Blog), we discussed pH and how it’s measured. In this issue of The Wine Analyst’s Blog, we’ll learn more about pH, TA, and how to understand and manage them in winemaking.  We’ll also look at yeast assimilable nitrogen (YAN) which uses the TA system. Keep Reading More!

For years it has been said that the Ripper method for measuring sulfite (SO2) has one drawback: interference from “reductones”. These are substances that react with the iodine titrant as SO2 itself does, causing an overestimation of the true SO2 level. But as we’ll see below, this does not seem to be a huge problem with the Vinmetrica version of the Ripper method, and where encountered, it can usually be corrected for.
The Ripper method uses iodine or iodine-generating reagents to oxidize the SO2 in the test sample (primarily wine, but beer and cider are also examples). It relies on the quantitative reaction of iodine (I2) oxidizing the SO2 in the sample under acid conditions.

In this reaction, SO2 is acting as a “reductant” for the oxidant iodine. When all the SO2 is oxidized by iodine at the endpoint, excess iodine appears in solution. The Vinmetrica system detects this event as a sharp rise in electrochemical current with its SO2 electrode.
Anything in the sample that reacts like a reductant – called a “reductone” – in a Ripper titration will appear to be SO2, leading to an overestimation of the SO2 level. A well-known example of a reductone is ascorbic acid. Ascorbic acid (“AA”, also known as ascorbate or vitamin C) reacts with iodine just as SO2 does, that is

Ascorbic acid can be found in modest amounts in some vinifera varietals, and it can occur in high levels in a number of fruits, like citrus and some berries. When trying to measure SO2 levels in these samples, one must be careful not to get misled by ascorbate parading as SO2!
There are other things present in wines and juices that can act as reductones. In principle, reducing sugars (glucose, fructose) and various polyphenols could act as reductones.

How to correct for reductones:

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Vinmetrica Compares Well with Wine Testing Labs

Summary: Vinmetrica is participating in the CTS Wine Industry Interlaboratory Program this year. Along with 100 other labs, we tested two samples from CTS for up to 16 parameters. Using our products, we obtained results for free and total SO2, pH, TA, malic acid, and residual sugar that were in good agreement with those of the other participants.

We are pleased to report the first round of results from participating in Collaborative Testing Services’ (CTS) Wine Industry Interlaboratory Program for 2020. CTS (www.collaborativetesting.com) provides samples to, and analysis of the results from, participating laboratories in a wide variety of testing technologies. The Wine Industry Interlaboratory Program focuses on chemical and physical analysis of wine.

This last round of samples from CTS (“Cycle 065”) comprised two sweet red wines. About 100 labs across the US participated. The following parameters were available to be measured and compared: Total SO2, Free SO2, TA, pH, Residual Reducing Sugars, L-malic acid, %ABV, Specific Gravity, Glucose + Fructose, Copper, Potassium, A420, A520, L-lactic acid, Conductivity, and Methanol. We submitted results for all these except Copper, A420, and A520, the first because we don’t have the equipment for it, the latter two because we rarely perform them (though we can do so). Keep Reading More!